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Preheat the oven to 200°F / 90°C.
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Combine the cream, milk, 1/2 cup of granulated sugar, and instant coffee in a medium heavy saucepan.
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Using a spoon, scrape the seeds from the vanilla bean into the cream mixture and whisk to blend. Add the scraped vanilla bean.
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Bring the cream mixture to a near boil over medium-high heat, stirring until the sugar and coffee dissolve.
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Remove from the heat and cool for 5 minutes.
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Whisk the yolks in a large bowl to blend.
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Gradually whisk in the warm cream mixture to blend.
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Strain the custard through a fine-meshed strainer and into a 4-cup measuring cup.
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Place four 5-ounce custard cups or ovenproof coffee cups in a baking dish.
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Divide the custard among the custard cups in the baking dish.
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Place the baking dish in the oven. Fill the baking dish halfway with hot water.
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Bake the custards uncovered for 2 hours, or until the centers move only slightly when the cups are gently shaken (the custards will become firm as they cool).
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Remove the custards from the baking dish and let cool, then place the custards in the refrigerator until cold.
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Sprinkle the sugar over the custards.
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Using a kitchen blow torch, wave the flame over the custards until the sugar caramelizes.
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Refrigerate the custards until the topping is cold and brittle, about 10 minutes, then serve.